Study of migration and transformation of greasing and cooling fluids in the soil of urbanized area
L. M. Shuklina, G. M. Batrakova, T. N. Nurislamova
Section: Ecologization of industry
Relevance of the work is determined by the requirements of ecological safety in the industrial and civil construction
in areas with identified technogenic soils’ pollution. The paper considers the use of chromatography-mass spectrometry
in a study of polluted soil in order to identify transformation products under natural conditions of multicomponent formulas
of lubricating fluids. The identification and search by mass spectra of the component composition of the industrial
oil transformation products was carried out, a marker compound is proposed. The possibility of structure and element
composition identification on the basis of registration of mass spectra of chemical compounds is shown. The search for
characteristic ions of organic compounds was carried out using a bank of the mass-spectral data library. The characteristic ions (basic and sustaining) describing the structure of chemical compounds and the chromatographic retention time
are determined. To assess the migration of the marker compound, a quantitative determination of the marker compound
was made by capillary gas chromatography in air and polluted soils samples. Soil samples at the bottom of the vessel,
samples of oil-retaining tissue and filtrate from the pallet were examined.
The results of the research are aimed at justifying the method for assessing the contamination of industrial sites
with lubricating fluids, taking into account the transformation of the organic pollutant and recommendations for the
recultivation of polluted technozems.
ISSN 1995-4301
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