<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Archiving and Interchange DTD with OASIS Tables with MathML3 v1.4 20241031//EN" "https://jats.nlm.nih.gov/archiving/1.4/JATS-archive-oasis-article1-4-mathml3.dtd">
<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" dtd-version="1.4" article-type="research-article" xml:lang="en"><front><journal-meta><journal-title-group><journal-title xml:lang="ru">Теоретическая и прикладная экология</journal-title></journal-title-group><issn publication-format="print">1995-4301</issn><issn publication-format="electronic">2618-8406</issn></journal-meta><article-meta><article-id pub-id-type="doi">10.25750/1995-4301-2026-3-141-153</article-id><article-categories><subj-group><subject>Other</subject></subj-group></article-categories><title-group><article-title xml:lang="ru">Эколого-экономическая эффективность малотоннажного производства метанола на основе газогенераторов синтез-газа</article-title><trans-title-group xml:lang="en"><trans-title>Environmental and economic efficiency of small-scale methanol production based on syngas generators</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author"><name-alternatives><name xml:lang="ru"><surname>Кузьмин</surname><given-names>A. M.</given-names></name><name xml:lang="en"><surname>Kuzmin</surname><given-names>A. M.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff1"/><xref ref-type="aff" rid="aff2"/><xref ref-type="aff" rid="aff3"/><xref ref-type="aff" rid="aff4"/><email>kuzmin.lex@gmail.com</email><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-0153-5683</contrib-id></contrib><contrib contrib-type="author"><name-alternatives><name xml:lang="ru"><surname>Гашевский</surname><given-names>E. M.</given-names></name><name xml:lang="en"><surname>Gashevskiy</surname><given-names>E. M.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff5"/><xref ref-type="aff" rid="aff6"/><email>em@gashevskiy.ru</email><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-3919-954X</contrib-id></contrib><aff-alternatives id="aff1"><aff><institution xml:lang="en">National Research Tomsk Polytechnic University</institution><city xml:lang="en">Tomsk</city><country xml:lang="en">Russia</country></aff></aff-alternatives><aff-alternatives id="aff2"><aff><institution xml:lang="en">LLC "HTR"</institution><city xml:lang="en">Saint Petersburg</city><country xml:lang="en">Russia</country></aff></aff-alternatives><aff-alternatives id="aff3"><aff><institution xml:lang="ru">Национальный исследовательский Томский политехнический университет</institution><city xml:lang="ru">Томск</city><country xml:lang="ru">Россия</country></aff></aff-alternatives><aff-alternatives id="aff4"><aff><institution xml:lang="ru">ООО "ВТР"</institution><city xml:lang="ru">Санкт-Петербург</city><country xml:lang="ru">Россия</country></aff></aff-alternatives><aff-alternatives id="aff5"><aff><institution xml:lang="en">Baltic State Technical University "VOENMEH" named after D. F. Ustinov</institution><city xml:lang="en">Saint Petersburg</city><country xml:lang="en">Russia</country></aff></aff-alternatives><aff-alternatives id="aff6"><aff><institution xml:lang="ru">Балтийский государственный технический университет "ВОЕНМЕХ" им. Д. Ф. Устинова</institution><city xml:lang="ru">Санкт-Петербург</city><country xml:lang="ru">Россия</country></aff></aff-alternatives></contrib-group><pub-date pub-type="epub" iso-8601-date="2026-09-29"><day>29</day><month>09</month><year>2026</year></pub-date><issue>3</issue><fpage>141</fpage><lpage>153</lpage><self-uri xlink:href="http://www.envjournal.ru/arhvr.php?q=1039" xlink:title="http://www.envjournal.ru/arhvr.php?q=1039">http://www.envjournal.ru/arhvr.php?q=1039</self-uri><self-uri content-type="pdf" xlink:href="publication-cb66a5a8-7b4f-4483-961c-ce0d109a3c16.pdf" xlink:title="PDF"/><abstract xml:lang="ru"><p>Рассмотрена проблема обеспечения метанолом отдалённых нефтегазовых месторождений. Показано, что традиционная схема транспортировки сопряжена с высокими экологическими рисками, обусловленными возможными утечками и загрязнением окружающей среды. В качестве альтернативы предложено создание мобильных малотоннажных установок производства метанола на основе некаталитического парциального окисления метана в газогенераторе синтез-газа (ГСГ). Приведены результаты численного моделирования внутрикамерных процессов для производительности 5000 т метанола в год. Установлено, что оптимизация смесительной головки позволяет достичь полноты сгорания метана на уровне 99,2 % при отсутствии сажеобразования и минимальном остаточном содержании метана. На основе методологии оценки жизненного цикла (LCA) выполнял расчёт углеродного следа. Показано, что локальное производство метанола снижает удельные выбросы парниковых газов на 40-58 % по сравнению с централизованным производством и транспортировкой на расстояние от 2000-5000 км. Представлены результаты технико-экономической оценки для производительностей 2500-10000 т/год, включая показатели CAPEX, OPEX, себестоимости, IRR, NPV и срока окупаемости. Выполнен системный анализ экологических и технологических рисков внедрения ГСГ-установок, включая пожарои взрывоопасность, с обоснованием мер их минимизации. Сделан вывод о том, что внедрение ГСГ-установок существенно снижает экологическую нагрузку на труднодоступных территориях за счёт исключения дальних перевозок опасного груза и уменьшения эмиссии парниковых газов.</p></abstract><abstract xml:lang="en" abstract-type="summary"><p>The paper addresses the problem of methanol supply to remote oil and gas fields. It is shown that the traditional transportation scheme involves high environmental risks due to potential spills and pollution. As an alternative, the development of mobile small-scale methanol production units based on non-catalytic partial oxidation of methane in a syngas generator (SGG) is proposed. The results of numerical simulation of in-chamber processes for methanol capacity of 5000 t/year are presented. It is established that optimization of the mixing head allows achieving methane combustion efficiency of 99.2 % without soot formation and with minimal residual methane. Based on life cycle assessment (LCA) methodology, the carbon footprint was calculated. It is shown that on-site methanol production reduces specific green house gas emissions by 40–58 % compared with centralized production and transportation over a distance of 2000–5000 km. The results of a techno-economic assessment for capacities of 2500–10000 t/year are presented, including CAPEX, OPEX, production cost, IRR, NPV and payback period. A systematic analysis of environmental and technological risks of SGG implementation, including fire and explosion hazards, with justification of mitigation measures, has been performed. It is concluded that the implementation of SGG-based units significantly reduces the environmental pressure in remote areas by eliminating long-distance hazardous cargo transportation and decreasing green house gas emissions.</p></abstract><kwd-group xml:lang="ru"><kwd>синтез-газ</kwd><kwd>метанол</kwd><kwd>малотоннажное производство</kwd><kwd>газогенератор</kwd><kwd>парциальное окисление</kwd><kwd>экологические риски</kwd><kwd>численное моделирование</kwd><kwd>выбросы</kwd><kwd>попутный нефтяной газ</kwd><kwd>углеродный след</kwd><kwd>масштабирование</kwd></kwd-group><kwd-group xml:lang="en"><kwd>syngas</kwd><kwd>methanol</kwd><kwd>small-scale production</kwd><kwd>gas generator</kwd><kwd>partial oxidation</kwd><kwd>environmental risks</kwd><kwd>numerical simulation</kwd><kwd>emissions</kwd><kwd>associated petroleum gas</kwd><kwd>carbon footprint</kwd><kwd>scaling</kwd></kwd-group></article-meta></front><back><ref-list><ref id="ref1"><mixed-citation publication-type="other" xml:lang="ru">Кемалов Р.А., Кемалов А.Ф. Технологии получения и применения метанола. Казань: Казан. ун-т, 2016. 167 с.</mixed-citation></ref><ref id="ref2"><mixed-citation publication-type="other" xml:lang="ru">Арутюнов В.С., Голубева И.А., Елисеев О.Л., Жагфаров Ф.Г. Технология переработки углеводородных газов. М.: Юрайт, 2020. 723 с.</mixed-citation></ref><ref id="ref3"><mixed-citation publication-type="other" xml:lang="ru">Арутюнов В.С. Окислительная конверсия природного газа. М.: Красанд, 2011. 590 с.</mixed-citation></ref><ref id="ref4"><mixed-citation publication-type="other" xml:lang="ru">Magson J., Lee Chan T.G., Mohammed A., Ward K. Towards flexible large‑scale, environmentally sustainable methanol and ammonia co‑production using industrial symbiosis // RSC Sustainability. 2025. V. 3. No. 3. P. 1157–1169. doi: 10.1039/d4su00647j</mixed-citation></ref><ref id="ref5"><mixed-citation publication-type="other" xml:lang="ru">Кузьмин А.М. Попутный нефтяной газ в метанол: экологические последствия факельного сжигания и перспективы низкоуглеродной энергетики (обзор) // Теоретическая и прикладная экология. 2026. № 2. С. 29–39. doi: 10.25750/1995-4301-2026-2-029-039</mixed-citation></ref><ref id="ref6"><mixed-citation publication-type="other" xml:lang="ru">Кантор Г.Я., Сырчина Н.В. Альтернативная оценка вклада метана в парниковый эффект // Теоретическая и прикладная экология. 2023. № 3. С. 197–207. doi: 10.25750/1995-4301-2023-3-197-207</mixed-citation></ref><ref id="ref7"><mixed-citation publication-type="other" xml:lang="ru">Launder B.E., Spalding D.B. The numerical computation of turbulent flows // Comput. Methods Appl. Mech. Eng. 1974. V. 3. No. 2. P. 269–289. doi: 10.1016/0045-7825(74)90029-2</mixed-citation></ref><ref id="ref8"><mixed-citation publication-type="other" xml:lang="ru">Magnussen B.F., Hjertager B.H. On mathematical modeling of turbulent combustion with special emphasis on soot formation and combustion // Symp. Combust. Proc. 1977. V. 16. No. 1. P. 719–729. doi:10.1016/S0082- 0784(77)80366-4</mixed-citation></ref><ref id="ref9"><mixed-citation publication-type="other" xml:lang="ru">Bouziane A., Alami A., Zaitri M., Bouchame B., Bouchetara M. Investigation of swirl stabilized CH4 air flame with varied hydrogen content by using computational fluid dynamics (CFD) to study the temperature field and flame shape // Eng. Technol. Appl. Sci. Res. 2021. V. 11. No. 2. P. 6943–6948. doi: 10.48084/etasr.4034</mixed-citation></ref><ref id="ref10"><mixed-citation publication-type="other" xml:lang="ru">Кузьмин А.М., Гашевский Е.М. Исследование термодинамических процессов парциального окисления в газогенераторе синтез-газа // Научный журнал Российского газового общества. 2023. № 1. С. 106–112. doi: 10.55557/2412-6497-2023-1-106-112</mixed-citation></ref><ref id="ref11"><mixed-citation publication-type="other" xml:lang="ru">Кочуров Б.И., Глуховская М.Ю., Гарицкая М.Ю., Евстифеева Т.А. О методических подходах к определению углеродного следа // Теоретическая и прикладная экология. 2023. № 4. С. 216–224. doi: 10.25750/1995-4301-2023-4-216-224</mixed-citation></ref><ref id="ref12"><mixed-citation publication-type="other" xml:lang="ru">Prifti K., Lechtenberg F., Manenti F., Espuña A., Graells M. Comparing the climate impact of methanol production in Europe: Steam methane reforming vs. Plastic waste gasification processes // Resour. Conserv. Recycl. 2024. V. 208. Article No. 107653. doi: 10.1016/j. resconrec.2024.107653</mixed-citation></ref><ref id="ref13"><mixed-citation publication-type="other" xml:lang="ru">Makaryan I.A., Salgansky E.A., Arutyunov V.S., Sedov I.V. Non-catalytic partial oxidation of hydrocarbon gases to syngas and hydrogen: a systematic review // Energies. 2023. V. 16. No. 6. Article No. 2916. doi: 10.3390/ en16062916</mixed-citation></ref><ref id="ref14"><mixed-citation publication-type="other" xml:lang="ru">Masum F.H., Tan E.C.D., Kolodziej C.P., Hawkins T.R. Life cycle assessment of methanol from fossil, biomass, and waste sources, and its use as a marine fuel in dual-fuel engines // Environ. Sci. Technol. 2025. V. 59. No. 43. P. 23239–23250. doi: 10.1021/acs.est.5c08873</mixed-citation></ref><ref id="ref15"><mixed-citation publication-type="other" xml:lang="ru">Al-Yafei H., Aseel S., AlNouss A., AlJarrah M., Abdussamie N., Al-Kuwari A., Kerret A., Ghafoor N.A., Winarno M.R., Al-Bader A., Al Tamimi T., Sabbah S. Driving Green: a comprehensive sustainability analysis of natural gas-to-methanol and methanol-to-gasoline supply chains // Sustainability. 2026. V. 18. No. 1. Article No. 527. doi: 10.3390/su18010527</mixed-citation></ref><ref id="ref16"><mixed-citation publication-type="other" xml:lang="ru">Climate Change 2021: The Physical Science Basis. Contribution of Working Group I to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change / Eds. V. Masson-Delmotte, P. Zhai, A. Pirani, S.L. Connors, C. Péan, Y. Chen, L. Goldfarb, M.I. Gomis, J.B.R. Matthews, S. Berger, M. Huang, O. Yelekçi, R. Yu, B. Zhou, E. Lonnoy, T.K. Maycock, T. Waterfield, K. Leitzell, N. Caud. Intergovermental Panel on Climate Change, 2021. 40 p.</mixed-citation></ref><ref id="ref17"><mixed-citation publication-type="other" xml:lang="ru">Vasilyev A.V. Complex ecological monitoring of negative impact of oil-containing waste in areas of oilfields as an object of ecological risk // Theoretical and Applied Ecology. 2023. No. 4. P.  78–84. doi: 10.25750/1995-4301-2023-4-078-084</mixed-citation></ref><ref id="ref18"><mixed-citation publication-type="other" xml:lang="ru">Загашвили Ю.В., Ефремов В.Н., Кузьмин А.М., Лищинер И.И. Комплекс получения синтез-газа для малотоннажного производства метанола // НефтеГазо- Химия. 2017. № 1.С. 19–26.</mixed-citation></ref><ref id="ref19"><mixed-citation publication-type="other" xml:lang="ru">Кузьмин А.М., Гашевский Е.М., Кузьмина Ю.В. Обоснование геометрических характеристик газогенератора синтез-газа // Научный журнал Российского газового общества. 2023. № 3. С. 104–117.</mixed-citation></ref><ref id="ref20"><mixed-citation publication-type="other" xml:lang="ru">Кузьмин А.М., Улманис А.А., Ценева С.Н., Буслаев Г.В., Морин А.А. Технико-экономическая оценка технологии малотоннажного производства метанола при парциальном окислении природного газа воздухом // Нефтегазовое дело. 2022. № 1. С. 144–169. doi: 10.17122/ ogbus-2022-1-144-169</mixed-citation></ref><ref id="ref21"><mixed-citation publication-type="other" xml:lang="ru">Брейли Р., Майерс С. Принципы корпоративных финансов. М.: Олимп-Бизнес, 2016. 1008 с.</mixed-citation></ref><ref id="ref22"><mixed-citation publication-type="other" xml:lang="ru">Загашвили Ю.В., Кузьмин А.М. Оптимизация состава синтез-газа для малотоннажного производства метанола // НефтеГазоХимия. 2018. № 3. С. 39–43. doi: 10.24411/2310-8266-2018-10303</mixed-citation></ref><ref id="ref23"><mixed-citation publication-type="other" xml:lang="ru">Загашвили Ю.В., Кузьмин А.М. Влияние состава водородсодержащего газа на выход метанола // Известия Томского политехнического университета. Инжиниринг георесурсов. 2020. Т. 331. № 10. С. 187–195. doi: 10.18799/24131830/2020/10/2871</mixed-citation></ref><ref id="ref24"><mixed-citation publication-type="other" xml:lang="ru">Lishchiner I.I., Malova O.V., Tarasov A.L. Conversion of associated petroleum gas into aromatic hydrocarbons // Catal. Ind. 2019. V. 11. No. 2. P. 138–146. doi: 10.1134/S2070050419020077</mixed-citation></ref><ref id="ref25"><mixed-citation publication-type="other" xml:lang="ru">Лищинер И.И., Малова О.В., Толчинский Л.С. Модульные энерготехнологические установки Энергосинтоп // Газохимия: состояние и пути развития в XXI веке: труды Московского семинара по газохимии 2012–2013 гг. М.: РГУ нефти и газа им. И.М. Губкина, 2014. С. 140–160.</mixed-citation></ref><ref id="ref26"><mixed-citation publication-type="other" xml:lang="en">Kemalov R.A., Kemalov A.F. Technologies for methanol production and application. Kazan: Kazan University Publ., 2016. 167 p. (in Russian).</mixed-citation></ref><ref id="ref27"><mixed-citation publication-type="other" xml:lang="en">Arutyunov V.S., Golubeva I.A., Eliseev O.L., Zhagfarov F.G. Technology of hydrocarbon gas processing. Moskva: Yurayt Publ., 2020. 723 p. (in Russian).</mixed-citation></ref><ref id="ref28"><mixed-citation publication-type="other" xml:lang="en">Arutyunov V.S. Oxidative conversion of natural gas. Moskva: Krasand Publ., 2011. 590 p. (in Russian).</mixed-citation></ref><ref id="ref29"><mixed-citation publication-type="other" xml:lang="en">Magson J., Lee Chan T.G., Mohammed A., Ward K. Towards flexible large-scale, environmentally sustainable methanol and ammonia co production using industrial symbiosis // RSC Sustainability. 2025. V. 3. No. 3. P. 1157–1169. doi: 10.1039/d4su00647j</mixed-citation></ref><ref id="ref30"><mixed-citation publication-type="other" xml:lang="en">Kuzmin A.M. Associated petroleum gas processing into methanol: environmental impacts of flaring and prospects for low-carbon energy: a review // Theoretical and Applied Ecology. 2026. No. 2. P. 29–39 (in Russian). doi: 10.25750/1995-4301-2026-2-029-039</mixed-citation></ref><ref id="ref31"><mixed-citation publication-type="other" xml:lang="en">Kantor G.Ya., Syrchina N.V. Alternative assessment of methane’s contribution to the greenhouse effect // Theoretical and Applied Ecology. 2023. No. 3. P. 197–207 (in Russian). doi: 10.25750/1995-4301-2023-3-197-207</mixed-citation></ref><ref id="ref32"><mixed-citation publication-type="other" xml:lang="en">Launder B.E., Spalding D.B. The numerical computation of turbulent flows // Comput. Methods Appl. Mech. Eng. 1974. V. 3. No. 2. P. 269–289. doi: 10.1016/0045- 7825(74)90029-2</mixed-citation></ref><ref id="ref33"><mixed-citation publication-type="other" xml:lang="en">Magnussen B.F., Hjertager B.H. On mathematical modeling of turbulent combustion with special emphasis on soot formation and combustion // Symp. Combust. Proc. 1977. V. 16. No. 1. P. 719–729. doi: 10.1016/S0082- 0784(77)80366-4</mixed-citation></ref><ref id="ref34"><mixed-citation publication-type="other" xml:lang="en">Bouziane A., Alami A., Zaitri M., Bouchame B., Bouchetara M. Investigation of swirl stabilized CH4 air flame with varied hydrogen content by using computational fluid dynamics (CFD) to study the temperature field and flame shape // Eng. Technol. Appl. Sci. Res. 2021. V. 11. No. 2. P. 6943–6948. doi: 10.48084/etasr.4034</mixed-citation></ref><ref id="ref35"><mixed-citation publication-type="other" xml:lang="en">Kuzmin A.M., Gashevskiy E.M. Investigation of thermodynamic processes of partial oxidation in a synthesis gas generator // Scientific journal of Russian Gas Society. 2023. No. 1. P. 106–112 (in Russian). doi: 10.55557/2412-</mixed-citation></ref><ref id="ref36"><mixed-citation publication-type="other" xml:lang="en">Kochurov B.I., Glukhovskaya M.Yu., Garitskaya M.Yu., Evstifeeva T.A. On methodological approaches to determining the carbon footprint // Theoretical and Applied Ecology. 2023. No. 4. P. 216–224 (in Russian). doi: 10.25750/1995-4301-2023-4-216-224</mixed-citation></ref><ref id="ref37"><mixed-citation publication-type="other" xml:lang="en">Prifti K., Lechtenberg F., Manenti F., Espuña A., Graells M. Comparing the climate impact of methanol production in Europe: Steam methane reforming vs. Plastic waste gasification processes // Resour. Conserv. Recycl. 2024. V. 208. Article No. 107653. doi: 10.1016/j.resconrec.2024.107653</mixed-citation></ref><ref id="ref38"><mixed-citation publication-type="other" xml:lang="en">Makaryan I.A., Salgansky E.A., Arutyunov V.S., Sedov I.V. Non-catalytic partial oxidation of hydrocarbon gases to syngas and hydrogen: a systematic review // Energies. 2023. V. 16. No. 6. Article No. 2916. doi: 10.3390/en16062916</mixed-citation></ref><ref id="ref39"><mixed-citation publication-type="other" xml:lang="en">Masum F.H., Tan E.C.D., Kolodziej C.P., Hawkins T.R. Life cycle assessment of methanol from fossil, biomass, and waste sources, and its use as a marine fuel in dual-fuel engines // Environ. Sci. Technol. 2025. V. 59. No. 43. P. 23239–23250. doi: 10.1021/acs.est.5c08873</mixed-citation></ref><ref id="ref40"><mixed-citation publication-type="other" xml:lang="en">Al-Yafei H., Aseel S., AlNouss A., AlJarrah M., Abdussamie N., Al-Kuwari A., Kerret A., Ghafoor N.A., Winarno M.R., Al-Bader A., AlTamimi T., Sabbah S. Driving Green: a comprehensive sustainability analysis of natural gas-to-methanol and methanol-to-gasoline supply chains // Sustainability. 2026. V. 18. No. 1. Article No. 527. doi: 10.3390/su18010527</mixed-citation></ref><ref id="ref41"><mixed-citation publication-type="other" xml:lang="en">Climate Change 2021: The Physical Science Basis. Contribution of Working Group I to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change / Eds. V. Masson-Delmotte, P. Zhai, A. Pirani, S.L. Connors, C. Péan, Y. Chen, L. Goldfarb, M.I. Gomis, J.B.R. Matthews, S. Berger, M. Huang, O. Yelekçi, R. Yu, B. Zhou, E. Lonnoy, T.K. Maycock, T. Waterfield, K. Leitzell, N. Caud. Intergovermental Panel on Climate Change, 2021. 40 p.</mixed-citation></ref><ref id="ref42"><mixed-citation publication-type="other" xml:lang="en">Vasilyev A.V. Complex ecological monitoring of negative impact of oil-containing waste in areas of oil fields as an object of ecological risk // Theoretical and Applied Ecology. 2023. No. 4. P. 78–84. doi: 10.25750/1995-4301-2023-4-078-084</mixed-citation></ref><ref id="ref43"><mixed-citation publication-type="other" xml:lang="en">Zagashvili Yu.V., Efremov V.N., Kuzmin A.M., Lischiner I.I. Complex for obtaining synthesis-gas for small-tonnage production of methanol // NefteGazoKhimiya. 2017. No. 1. P. 19–26 (in Russian).</mixed-citation></ref><ref id="ref44"><mixed-citation publication-type="other" xml:lang="en">Kuzmin A.M., Gashevskiy E.M., Kuzmina Yu.V. Substantiation of the geometric characteristics of a synthesis gas generator // Scientific journal of Russian Gas Society. 2023. No. 3. P. 104–117 (in Russian).</mixed-citation></ref><ref id="ref45"><mixed-citation publication-type="other" xml:lang="en">Kuzmin A.M., Ulmanis A.A., Tseneva S.N., Buslaev G.V., Morin A.A. Technical and economic assessment of low-tonnage methanol production technology under partial oxidation of natural gas by air // Oil and Gas Business. 2022. No. 1. P. 144–169 (in Russian). doi: 10.17122/ ogbus-2022-1-144-169</mixed-citation></ref><ref id="ref46"><mixed-citation publication-type="other" xml:lang="en">Brealey R.A., Myers S.C. Principles of corporate finance. Moskva: Olimp-Biznes, 2016. 1008 p. (in Russian).</mixed-citation></ref><ref id="ref47"><mixed-citation publication-type="other" xml:lang="en">Zagashvili Yu.V., Kuzmin A.M. Optimization of syngas composition for small-scale methanol production // NefteGazoKhimiya. 2018. No. 3. P. 39–43 (in Russian). doi: 10.24411/2310-8266-2018-10303</mixed-citation></ref><ref id="ref48"><mixed-citation publication-type="other" xml:lang="en">Zagashvili Yu.V., Kuzmin A.M. Influence of hydrogen-containing gas composition on methanol yield // Bulletin of the Tomsk Polytechnic University. Geo Assets Engineering. 2020. V. 331. No. 10. P. 187–195 (in Russian). doi: 10.18799/24131830/2020/10/2871</mixed-citation></ref><ref id="ref49"><mixed-citation publication-type="other" xml:lang="en">Lishchiner I.I., Malova O.V., Tarasov A.L. Conversion of associated petroleum gas into aromatic hydrocarbons // Catal. Ind. 2019. V. 11. No. 2. P. 138–146. doi: 10.1134/S2070050419020077</mixed-citation></ref><ref id="ref50"><mixed-citation publication-type="other" xml:lang="en">Lishchiner I.I., Malova O.V., Tolchinsky L.S. Modular energy-technology units Energosintop // Gas chemistry: state and ways of development in the 21st century: trudy Moskovskogo seminara po gazokhimii 2012–2013. Moskva: Gubkin Russian State University of Oil and Gas, 2014. P. 140–160 (in Russian).</mixed-citation></ref></ref-list></back></article>
