Теоретическая и прикладная экология1995-43012618-840610.25750/1995-4301-2026-3-131-140OtherОчистка газовых выбросов нефтегазоконденсатных месторождений на гетерогенном катализаторе (на примере Среднеботубинского месторождения)Purification of gas emissions of Srednebotuobinskoe oil-gas condensate field on a heterogeneous catalystИвановаM. C.IvanovaM. S.ims.06@mail.ruhttps://orcid.org/0000-0003-3272-9253ТомскийK. O.TomskiiK. O.https://orcid.org/0000-0001-7612-5393North-Eastern Federal UniversityYakutskRussiaСеверо-Восточный федеральный университет имени М. К. АммосоваЯкутскРоссия290920263131140http://www.envjournal.ru/arhvr.php?q=812

Образующиеся при сгорании углеводородного топлива диоксиды углерода и серы могут улавливаться несколькими способами. Из них наиболее эффективным и экономически целесообразным способом является каталитический. Целью данной работы является изучение процесса каталитической очистки от диоксидов углерода и серы газов горения попутного нефтяного газа Среднеботубинского нефтегазоконденсатного месторождения (СБНГКМ) во фторсодержащих средах, таких как суспензии фторида кальция с различными концентрациями, и определение оптимальных параметров проведения процесса очистки от диоксидов углерода и серы в рассматриваемых суспензиях. Исследование каталитической очистки от диоксидов углерода и серы в среде суспензий фторидов кальция проводили при атмосферном давлении и температуре, равной 25°C. Диоксиды углерода и серы пропускали через систему, состоящую из суспензии фторида кальция с концентрациями в пределах от 0,05 М до 1,4 М. Для определения влияния скорости подачи очищаемых газов на сорбцию суспензией фторида кальция CO2 пропускали при скоростях подачи от 0,03 до 0,118 л/мин. Для восстановления каталитической способности отработанной суспензии фторида кальция через систему пропускали кислород воздуха в течение 1 ч. В результате проведённой регенерации каталитическая система полностью восстанавливала свои окислительные способности. В работе показана принципиальная возможность проведения каталитической очистки газов горения в среде фторида кальция от CO2 и SO2. На примере попутного нефтяного газа СБНГКМ определены оптимальные параметры очистки: скорость подачи газов в сорбент, равная 100 мл/мин, и концентрация каталитической системы, равная 0,4 моль/л.

Carbon and sulfur dioxide formed during the combustion of hydrocarbon fuels can be captured in several ways. Of these, catalytic capture is the most effective and cost-effective. The aim of this study was to investigate the catalytic removal of carbon dioxide and sulfur from associated petroleum gas combustion gases at the Srednebotuobinskoye oil and gas condensate field in fluorine-containing media, such as calcium fluoride suspensions with varying concentrations, and to determine the optimal parameters for the removal of carbon dioxide and sulfur from these suspensions. The catalytic removal of carbon dioxide and sulfur from calcium fluoride suspensions was studied at atmospheric pressure and a temperature of 25 оC. Carbon and sulfur dioxides were passed through a system consisting of a calcium fluoride suspension with concentrations ranging from 0.05 M to 1.4 M. To determine the effect of the feed rate of the gases being purified on the sorption of the calcium fluoride suspension, CO2 was passed at feed rates from 0.03 to 0.118 L/min. To restore the catalytic capacity of the spent calcium fluoride suspension, atmospheric oxygen was passed through the system for 1 hour. As a result of the regeneration, the catalytic system completely restored its oxidizing capacity. The study demonstrates the fundamental possibility of catalytic purification of combustion gases in a calcium fluoride environment to remove CO2 and SO2. Using the associated petroleum gas of the Srednebotuobinskoye oil condensate field as an example, the optimal purification parameters were determined: a gas feed rate to the sorbent of 100 mL/min and a catalytic system concentration of 0.4 mol/L.

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Article No. 125607. doi: 10.1016/j.fuel.2022.125607Ruan H., Wu S., Chen X., Zou J., Liao J., Cui H., Dong Y., Qiu Y., Shen J. Capturing CO2 with NaOH solution from reject brine via an integrated technology based on bipolar membrane electrodialysis and hollow fiber membrane contactor // Chem. Eng. J. 2022. V. 450. Article No. 138095. doi: 10.1016/j.cej.2022.138095Sooriyan S.K., Ibrahim N., Hanif M.A., Hasan M., Abdullah S., Adriansyah A.A., Setianto B., Syafiuddin A. Performance optimization of sulfur dioxide (SО2) desulfurization by oil palm-based activated carbon using box-behnken design // Biointerf. Res. Appl. Chem. 2022. V. 12. No. 6. P. 7972–798215. doi: 10.33263/ BRIAC126.79727982Hu X., Bobbink F.D., van Muyden A., Talebi Amiri M., Bonnin A., Maréchal F., Nazeeruddin M.K., Qi Z., Dyson P.J. Cycloaddition of biogas-contained CO2 into epoxides via ionic polymer catalysis: an experimental and process simulation study // Ind. Eng. Chem. Res. 2021. V. 60. No. 49. 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